외국도서

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대학교재/전문서적

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자연과학 일반

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• 제휴몰 주문 시 고객보상, 일부 이벤트 참여 및 증정품 증정, 하루/당일 배송에서 제외되므로 참고 바랍니다.

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• 도서  > 외국도서  > 대학교재/전문서적  > 자연과학 일반
• 도서  > 외국도서  > 대학교재/전문서적  > 기술과학 일반

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• Preface xv About the Author xvii Abbreviations xix 1 Basic Concepts 1 1.1 Introduction to Reaction Mechanisms 1 1.2 Covalent Bonding and Hybridization 2 1.2.1 sp3-Hybridization of Carbon 4 1.2.2 sp2-Hybridization of Carbon 7 1.2.3 sp-Hybridization of Carbon 10 1.2.4 Bond Lengths 12 1.3 Electrophiles and Nucleophiles 13 1.3.1 Electrophiles (Electrophilic Compounds) 14 1.3.2 Nucleophiles (Nucleophilic Compounds) 15 1.4 Inductive and Mesomeric Effects 15 1.4.1 Inductive Effect 15 1.4.2 Mesomeric Effect (Resonance Structures) 18 1.5 Formal Charge and Oxidation Number 24 1.5.1 Formal Charge 24 1.5.2 Oxidation Number 25 1.6 Acids and Bases 28 1.6.1 Arrhenius Acid?Base Theory 29 1.6.2 Brønsted?Lowry Acid?Base Theory 29 1.6.3 Lewis Acid?Base Theory 30 1.6.4 Pearson Hard and Soft Acid?Base Theory 32 1.6.4.1 Hard Acids and Bases 32 1.6.4.2 Soft Acids and Bases 33 1.6.5 pKa Values of Acids 34 1.6.5.1 Factors Affecting the Acidity Strength of Organic Compounds 35 1.6.6 pKb Values of Bases 38 1.6.7... Factors Affecting the Strengths of Bases in Nitrogen-Containing Compounds 38 1.6.8 Heterocyclic Bases 40 1.7 Reaction Kinetics and Energy Diagrams 41 1.7.1 Thermodynamic vs. Kinetic Control of Reactions 43 1.7.2 Reaction rate 44 Problems 46 References 48 2 Nucleophilic Substitution Reaction 50 2.1 Types of Chemical Reactions 50 2.1.1 Polar Reactions 50 2.1.2 Radical Reactions 50 2.1.3 Pericyclic Reactions 50 2.1.3.1 Relationship Between Nucleophilicity and Basicity 51 2.1.3.2 Leaving Group 54 2.2 Unimolecular Nucleophilic Substitution Reactions, SN1 55 2.2.1 Stereochemistry in SN1 Reactions 58 2.2.2 Optical Activity 59 2.2.3 Other Factors Affecting SN1 Reactions: Steric Factors 61 2.3 Bimolecular Substitution Reactions, SN2 62 2.3.1 Stereochemistry of SN2 Reactions 64 2.3.2 Factors Affecting the SN2 Reaction Mechanism 66 2.3.2.1 The Structure of the Substrate 66 2.3.2.2 Solvent Effect 68 2.3.2.3 Leaving Group Effect 69 2.3.2.4 Structure of the Nucleophile 70 2.3.3 Nucleophilic Substitution in Allylic Systems: Allylic Rearrangement 71 2.3.3.1 Stereochemistry in Allylic Substitution Reactions 73 2.3.4 Internal Nucleophilic Substitution Reaction, SNi 74 2.3.5 Neighboring Group Participation in Nucleophilic Substitution Reactions 75 2.3.5.1 Reaction Rate 76 2.3.5.2 Configuration Retention 77 2.3.5.3 Molecular Rearrangement 78 2.3.6 Ambident Nucleophiles 78 2.3.7 Various Nucleophilic Substitution Reactions 80 2.3.7.1 Williamson Ether Synthesis 80 2.3.7.2 Ether Cleavage 81 2.3.7.3 Reactions of Epoxides 82 2.3.7.4 Substitution in Unsaturated Systems 83 Problems 83 References 85 3 Elimination Reactions 87 3.1 Unimolecular Elimination Reactions, E1 88 3.1.1 E1 Reaction Mechanism 88 3.1.1.1 Dehydration of Alcohols 91 3.1.2 Factors Affecting the Ratio of E1 and SN1 92 3.2 Bimolecular Elimination Reactions, E2 94 3.2.1 Kinetic Isotope Effect 98 3.2.2 Stereochemistry in E2 Elimination Reactions 98 3.2.2.1 Erythro- and Threo-Configurations 100 3.2.3 E2 Elimination in the Cyclohexane System 105 3.2.3.1 Conformation and Configuration in Cyclohexane 105 3.2.3.2 syn-Elimination (cis-Elimination) 112 3.3 Unimolecular Conjugate Base Elimination, E1cb 112 3.4 Elimination Reaction in Synthesis 114 3.4.1 Halogen Elimination 114 3.4.2 Hofmann Elimination: Quaternary Ammonium Salts 116 3.4.3 Pyrolytic Elimination: Intramolecular cis-Elimination Reactions 119 3.4.4 Elimination at the Bridgehead: Bredt’s Rule 123 3.4.5 Grob Fragmentation 126 Problems 129 References 131 4 Addition Reactions to Alkenes 133 4.1 Halogen Addition to Alkenes: Halogenation 133 4.1.1 Stereochemistry of Halogen Addition 136 4.2 Addition of Hydrogen Halides to Alkenes: Markovnikov’s Rule 138 4.2.1 Anti-Markovnikov Addition of Hydrogen Halides to Alkenes 141 4.3 Addition of Water and Alcohols to Alkenes 143 4.3.1 Hydration 143 4.3.2 Alkoxylation 144 4.3.3 Formation of Halohydrins 145 4.4 Hydration Alkenes: Oxymercuration and Demercuration 146 4.5 Hydroboration of Alkenes: anti-Markovnikov Hydration 148 4.6 Oxidation of Alkenes 152 4.6.1 Epoxidation 152 4.6.2 Dioxirane 156 4.6.3 Epoxide Ring-Opening Reactions 157 4.6.4 Vicinal cis-Dihydroxylation 159 4.6.5 Dihydroxylation via PIFA 161 4.6.6 Enzymatic Dihydroxylation 162 4.6.7 Ozonolysis: Oxidative Cleavage of Alkenes 162 4.7 Reduction of Alkenes 165 4.7.1 Heterogeneous Catalytic Reduction 166 4.7.2 Homogeneous Catalytic Reduction 168 4.8 Addition to Conjugated Dienes 171 Problems 176 References 177 5 Carbonyl Compounds 181 5.1 Reactivity of the Carbonyl Group 181 5.1.1 Structure?Reactivity Relationships 183 5.2 Reactions of Carbonyl Compounds: Addition Reactions 186 5.2.1 Hydration: Addition ofWater to Carbonyl Groups 187 5.2.2 Hemiacetal Formation: Addition of Alcohols to Carbonyl Groups 190 5.2.2.1 Cyclic Acetals and Their Synthetic Application 191 5.2.2.2 What is the Protecting Group? 192 5.2.2.3 Protection of Diols 193 5.2.2.4 Formation of Thioacetals and Their Synthetic Application 193 5.2.2.5 Umpolung: Polarity Inversion of the Aldehyde Carbonyl Group 195 5.2.3 Reactions of Aldehydes and Ketones with Amines 196 5.2.3.1 Oximes 199 5.2.3.2 Hydrazones 199 5.3 Reduction of Carbonyl Groups 200 5.3.1 Wolff?Kishner Reduction (Under Basic Conditions) 200 5.3.2 Clemmensen Reduction (Under Acidic Conditions) 201 5.3.3 Metal Hydride Reduction of the Carbonyl Groups 201 5.3.3.1 Diisobutyl Aluminum Hydride (DIBAL) Reduction 203 5.3.3.2 Sodium Borohydride (NaBH4) Reduction 203 5.3.3.3 Reduction of Carboxylic Acids 205 5.3.3.4 Meerwein?Ponndorf?Verley Reduction and Oppenauer Oxidation 209 5.4 Reaction of Carbonyl Groups with Organometallic Compounds 210 5.4.1 Grignard Reagents 210 5.4.2 Reactions with Active Hydrogen-Containing Compounds 213 5.4.3 Reactions with Carbonyl Compounds 213 5.4.4 Stereochemistry 214 5.4.5 Reaction with Esters 215 5.4.6 Reactions with Different Functional Groups 215 5.5 Reaction of Carbonyl Groups with Ylides 218 5.5.1 Phosphonium Ylides and Wittig Reactions 219 5.5.2 Reaction Mechanism 219 5.5.3 Stable Ylides 220 5.5.4 Unstable Ylides 220 5.5.5 Wittig?Schlosser Reaction 221 5.5.6 Wittig?Horner Reaction 222 5.5.7 Horner?Wadsworth?Emmons Reaction (HWE Reaction) 223 5.5.8 Sulfur Ylides 224 5.5.9 Julia Olefination 226 5.5.10 Peterson Olefination 227 5.6 Reactivity of α-Carbon Atoms 228 5.6.1 Acidity of α-Hydrogens 228 5.6.2 Keto?Enol Tautomerism 229 5.6.3 Acid-Catalyzed Enolization 232 5.6.4 Base-Catalyzed Enolization 233 5.6.5 Kinetic and Thermodynamic Enolates 234 5.6.6 Enol and Enolate Reactions 235 5.6.6.1 Racemization of Chiral Ketones, α-Epimerization 235 5.6.6.2 α-Halogenation of Aldehydes and Ketones 237 5.6.7 α-Alkylation of Carbonyl Compounds 241 5.6.7.1 Stork Enamine Reaction 243 5.6.7.2 Enolates Derived from 1, 3-Dicarbonyl Compounds 245 5.6.7.3 Enolates, Ambident Nucleophiles: C vs. O Alkylation 249 5.7 Condensation Reactions of Carbonyl Compounds 251 5.7.1 Aldol Condensation 252 5.7.2 Crossed Aldol Condensation 254 5.7.3 Robinson Annulation 256 5.7.4 Claisen Ester Condensation 257 5.7.5 Crossed Claisen Ester Condensation 259 5.7.6 Dieckmann Condensation 260 5.7.7 Knoevenagel Condensation 261 5.7.8 Perkin Condensation 264 5.7.9 Stobbe Condensation 265 5.7.10 Role of Condensation Reactions in Synthetic Chemistry 266 5.8 Ester Hydrolysis Reactions 268 5.8.1 Ester Hydrolysis 269 5.8.2 Ester Hydrolysis under Basic Conditions 270 5.8.3 BAL2 Mechanism 271 5.8.4 Ester Hydrolysis under Acidic Conditions 272 5.8.5 Asymmetric Ester Hydrolysis 273 5.8.6 Transesterification 273 Problems 275 References 278 6 Aromaticity 281 6.1 Aromatic Compounds 281 6.1.1 Discovery and Structure of Benzene 281 6.1.2 Aromatic, Antiaromatic, and Nonaromatic Compounds 284 6.1.2.1 Aromatic Compounds 284 6.1.2.2 Antiaromatic Compounds 285 6.1.2.3 Nonaromatic Compounds 286 6.1.3 Determination of the Molecular Orbitals of Aromatic Compounds 287 6.1.4 What Are the Criteria for Aromaticity? How Does One Quantify Aromaticity? 288 6.1.4.1 Thermodynamic and Aromatic Resonance Stabilization Energy 288 6.1.4.2 Structural Evidence for Aromaticity 289 6.1.4.3 Magnetic Evidence for Aromaticity 289 6.1.5 Homoaromaticity 291 6.1.6 M?bius Aromaticity 293 6.2 Aromatic Ions 294 6.3 Annulenes 303 6.3.1 Cyclobutadiene 303 6.3.2 [10]Annulene 305 6.3.3 [12]Annulenes 307 6.3.4 [14] and Higher Annulenes 308 6.4 Aromaticity in Fused Systems 311 6.5 Aromaticity in Heterocyclic Compounds 314 6.5.1 Heteroaromatic Compounds with Three-Membered Ring 314 6.5.2 Heteroaromatic Compounds with a Five-Membered Ring 315 6.5.3 Heteroaromatic Compounds with Six-Membered Ring 323 6.5.3.1 Electrophilic Aromatic Substitution 324 6.5.3.2 Nucleophilic Aromatic Substitution 326 6.5.3.3 Pyridine N-Oxides 327 6.5.3.4 Electrophilic Substitution 328 6.5.3.5 Nucleophilic Substitution 328 6.5.3.6 Six-Membered Ring Heteroaromatic Compounds with Two Nitrogen Atoms 329 6.5.4 Heteroaromatic Compounds with a Seven-Membered Ring 330 6.5.4.1 Oxepine 330 6.5.4.2 1H-Azepine 331 6.5.4.3 Thiepine 332 6.6 Electrophilic Aromatic Substitution: Chemistry of Benzene 333 6.6.1 Halogenation of Benzene 335 6.6.2 Nitration 336 6.6.3 Sulfonation 337 6.6.4 Friedel?Crafts Acylation 338 6.6.5 Friedel?Crafts Alkylation 339 6.6.6 Clemmensen Reduction 341 6.6.7 Reactivity of Monosubstituted Benzene Derivatives 341 6.6.8 Directing Effects of Substituents: Activating Groups 344 6.6.9 Directing Effects of Substituents: Deactivating Groups 349 6.6.10 Electrophilic Aromatic Substitution on Disubstituted Benzenes 352 6.7 Functionalization of the Side-Chain Substituents of Benzene 354 6.7.1 Oxidation of the Side Chain of Alkylbenzenes 354 6.7.2 Halogenation of Side Chains of Alkylbenzenes 355 6.7.3 Arenediazonium Ion as an Electrophile 356 6.8 Nucleophilic Aromatic Substitution Reactions 357 6.8.1 Addition?Elimination Mechanism (SNAr Mechanism) 358 6.8.2 Reaction of Arenediazonium Salts with Nucleophiles 360 6.8.2.1 Reductive Dediazonization 360 6.8.3 Elimination?Addition Mechanism 363 6.9 Polycyclic Aromatic Compounds 365 6.9.1 Naphthalene 365 6.9.2 Benzenoid Aromatic Compounds 368 Problems 373 References 375 7 Reactive Intermediates: Carbocations 381 7.1 Structure and Stability of Carbocations 384 7.2 Generation of Carbocations 387 7.2.1 Ionization Mechanism 387 7.2.2 Electrophilic Addition to π Bonds 388 7.3 Detection of Carbocations 388 7.4 Reactions of Carbocations: Rearrangements 389 7.4.1 Reactions with Nucleophiles 389 7.4.2 Double-bond Formation by Proton Elimination 389 7.4.3 Rearrangement 389 7.4.4 Carbocation Rearrangement 390 7.4.5 Ethyl Carbocation 390 7.4.6 Isopropyl Carbocation 390 7.4.7 Cyclopentyl Carbocation 391 7.4.8 TheWagner?Meerwein Rearrangement 391 7.4.9 Pinacol Rearrangement 393 7.4.10 Tiffeneau?Demjanov Rearrangement 395 7.4.11 Dienone?Phenol Rearrangement 398 7.4.12 Neighboring Group Participation in Molecular Rearrangement (Anchimeric Assistance) 398 7.4.13 Nonclassical Carbocations 401 7.4.14 Nametkin Rearrangement 406 7.4.15 Hydride Shift 406 7.4.16 Base-induced Nucleophilic Rearrangements 408 7.4.17 Favorskii Rearrangement 408 7.4.18 Ramberg?B?cklund Rearrangement 411 7.4.19 Benzil?Benzilic Acid Rearrangement 412 7.5 Rearrangement to Electron-deficient Nitrogen 412 7.5.1 Beckmann Rearrangement 413 7.5.2 Neber Rearrangement 415 7.5.3 Stieglitz Rearrangement 416 7.6 Rearrangement to Electron-deficient Oxygen 416 7.6.1 Baeyer?Villiger Rearrangement (or Oxidation) 417 Problems 419 References 421 8 Reactive Intermediates Carbanions, Carbenes, and Nitrenes 424 8.1 Carbanions: Electrophilic Rearrangements 424 8.1.1 Stevens Rearrangement 425 8.1.2 Sommelet?Hauser Rearrangement 427 8.1.3 Wittig Rearrangement 429 8.2 Carbenes 429 8.2.1 Naming Carbenes 430 8.2.2 Structure and Reactivity of Carbenes 430 8.2.3 Inductive Effect 430 8.2.4 Mesomeric Effect 430 8.2.5 Carbene Generation 431 8.2.5.1 Carbene Precursors: Synthesis of Diazo Compounds 432 8.2.5.2 Bamford?Stevens Reaction 432 8.2.5.3 N-Nitrosoalkyl Urea Compounds 433 8.2.5.4 Diazirines 434 8.2.5.5 α-Elimination Method 435 8.2.5.6 Simmons?Smith Reaction 437 8.2.6 Carbene Reactions 438 8.2.6.1 Carbene Cycloaddition Reactions 439 8.2.6.2 Carbene Insertion Reactions 445 8.2.6.3 Carbene Rearrangements 446 8.3 Azides and Nitrenes 453 8.3.1 Nitrene Synthesis 454 8.3.1.1 Synthesis of Acyl Azides 455 8.3.2 Nitrene Rearrangements 455 8.3.2.1 Curtius Rearrangement 455 8.3.2.2 Schmidt Rearrangement 457 8.3.2.3 Lossen Rearrangement 457 8.3.2.4 Hofmann Rearrangement 458 8.3.3 Nitrene Cycloaddition Reactions 458 8.3.4 Nitrene Insertion Reactions 460 Problems 461 References 465 9 Reactive Intermediates: Radicals and Singlet Oxygen 468 9.1 Structure of Radicals and Their Stability 468 9.1.1 Generation of Radicals 471 9.1.2 Radical Reactions 472 9.1.2.1 Atom-Abstraction Reaction 472 9.1.2.2 Radical Combination and Disproportionation 475 9.1.2.3 Kolbe Electrolysis (Kolbe Reaction) 476 9.1.2.4 Hunsdiecker Reaction 477 9.1.2.5 Radical Addition to Alkenes 478 9.1.2.6 Manganese(III)-Mediated Oxidative Radical Additions to Alkenes 480 9.1.2.7 Birch Reduction 481 9.1.2.8 Di-π-methane Rearrangement 483 9.1.2.9 Diradicals Derived from Diazo Compounds 486 9.2 Singlet Oxygen 487 9.2.1 The Electronic Configuration of the Oxygen Molecule 487 9.2.2 Singlet Oxygen Generation 489 9.2.2.1 Generation of Photosensitized Singlet Oxygen 489 9.2.2.2 Chemical Sources for Singlet Oxygen 490 9.2.3 Reactions of Singlet Oxygen 492 9.2.3.1 Ene Reactions 492 9.2.3.2 [2+2] Cycloaddition Reactions 493 9.2.3.3 [4+2] Cycloaddition Reactions 495 9.2.3.4 Bicyclic Endoperoxides in Synthesis 496 References 497 10 Pericyclic Reactions 500 10.1 Frontier Molecular Orbitals 502 10.2 Electrocyclic Reactions 505 10.2.1 Thermal Electrocyclic Reactions 505 10.2.2 Photochemical Electrocyclic Reactions 506 10.2.3 Application of the Woodward?Hoffman Rules to Electrocyclic Reactions 508 10.2.3.1 Neutral Compounds 508 10.2.3.2 Ionic Compounds 510 10.3 Correlation Diagrams 512 10.3.1 Symmetry Elements 512 10.4 Cycloaddition Reactions 515 10.4.1 Stereoselectivity in Cycloaddition Reactions: Secondary Orbital Interactions 520 10.4.2 Factors Affecting the Rates of Cycloadditions 521 10.4.3 Coefficients of the Frontier Orbitals: Application to Regioselectivity in Diels?Alder Reactions 522 10.5 Sigmatropic Reactions 526 10.6 Cope and Claisen Rearrangements 530 10.6.1 Oxy-Cope Rearrangement 531 10.6.2 Claisen Rearrangement 532 Problems 533 References 535 11 Carbon?Carbon Coupling Reactions 537 11.1 History 537 11.2 Mizoroki?Heck Coupling Reaction 539 11.2.1 Regioselectivity 542 11.3 Stille Coupling Reaction 547 11.3.1 Synthesis of Organotin Compounds 550 11.4 Suzuki?Miyaura Coupling Reaction 552 11.5 Negishi Coupling Reaction 558 11.6 Sonogashira Coupling Reaction 562 11.7 Kumada Coupling Reaction 566 11.8 Hiyama Coupling Reaction 567 11.8.1 Hiyama?Denmark Coupling 569 11.9 Buchwald?Hartwig Coupling Reaction 570 11.10 Tsuji?Trost Coupling Reaction 571 11.11 Palladium-Catalyzed Carbonylation Reactions 573 11.11.1 Carbonylative Coupling Reactions with Organometallic Reagents 576 11.11.2 Mo(CO)6-Mediated Carbonylation 577 References 578 Solutions 583 Index 605
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• Balci, Metin [저]

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인터파크도서는 고객님의 단순 변심에 의한 교환과 반품에 드는 비용은 고객님이 지불케 됩니다. 단, 상품이나 서비스 자체의 하자로 인한 교환 및 반품은 무료로 반품 됩니다. 교환 및 반품이 가능한 경우 상품을 공급 받은 날로부터 7일이내 가능 공급받으신 상품의 내용이 표시, 광고 내용과 다르거나 다르게 이행된 경우에는 공급받은 날로부터 3개월 이내,    혹은 그사실을 알게 된 날 또는 알 수 있었던 날로부터 30일 이내 상품에 아무런 하자가 없는 경우 소비자의 고객변심에 의한 교환은 상품의 포장상태 등이 전혀 손상되지 않은 경우에 한하여 가능 교환 및 반품이 불가능한 경우 구매확정 이후(오픈마켓상품에 한함) 고객님의 책임 있는 사유로 상품 등이 멸실 또는 훼손된 경우    (단, 상품의 내용을 확인하기 위하여 포장 등을 훼손한 경우는 제외) 시간이 지남에 따라 재판매가 곤란할 정도로 물품의 가치가 떨어진 경우 포장 개봉되어 상품 가치가 훼손된 경우 다배송지의 경우 반품 환불 다배송지의 경우 다른 지역의 반품을 동시에 진행할 수 없습니다. 1개 지역의 반품이 완료된 후 다른 지역 반품을 진행할 수 있으므로, 이점 양해해 주시기 바랍니다. 중고상품의 교환 중고상품은 제한된 재고 내에서 판매가 이루어지므로, 교환은 불가능합니다. 오픈마켓 상품의 환불 오픈마켓상품에 대한 책임은 원칙적으로 업체에게 있으므로, 교환/반품 접수시 반드시 판매자와 협의 후 반품 접수를 하셔야하며,    반품접수 없이 반송하거나, 우편으로 보낼 경우 상품 확인이 어려워 환불이 불가능할 수 있으니 유의하시기 바랍니다.

배송예정일 안내 인터파크 도서는 모든 상품에 대해 배송완료예정일을 웹사이트에 표시하고 있습니다. <인터파크 직배송 상품> 상품은 월~토요일 오전 10시 이전 주문분에 대하여 당일 출고/당일 배송완료를 보장하는 상품입니다. 상품은 서울지역/평일 주문분은 당일 출고/익일 배송완료를 보장하며, 서울외지역/평일 주문분의 경우는 오후 6시까지 주문분에 대하여 익일 배송완료를 보장하는 상품입니다. (단, 월요일은 12시까지 주문에 한함) 상품은, 입고예정일(제품출시일)+택배사배송일(1일)에 배송완료를 보장합니다. ~ 상품은 유통특성상 인터파크에서 재고를 보유하지 않은 상품으로 주문일+기준출고일+택배사배송일(1일)에 배송완료를 보장합니다.(토/공휴일은 배송기간에 포함되지 않습니다.) ※기준출고일:인터파크가 상품을 수급하여 물류창고에서 포장/출고하기까지 소요되는 시간 <업체 직접배송/오픈마켓 상품> ~ 상품은 업체가 주문을 확인하고, 출고하기까지 걸리는 시간입니다. 주문일+기준출고일+택배사배송일(2일)에 배송완료를 보장합니다.(토/공휴일은 배송기간에 포함되지 않습니다.) ※5일이내 출고가 시작되지 않을시, 오픈마켓 상품은 자동으로 주문이 취소되며, 고객님께 품절보상금을 지급해 드립니다. 배송비 안내 도서(중고도서 포함)만 구매하시면 : 배송비 2,000원 (1만원이상 구매 시 무료배송) 음반/DVD만 구매하시면 : 배송비 1,500원 (2만원이상 구매 시 무료배송) 잡지/만화/기프트만 구매하시면 : 배송비 2,000원 (2만원이상 구매 시 무료배송) 도서와 음반/DVD를 함께 구매하시면 : 배송비 1,500원 1만원이상 구매 시 무료배송) 도서와 잡지/만화/기프트/중고직배송상품을 함께 구매하시면 : 2,000원 (1만원이상 구매 시 무료배송) 업체직접배송상품을 구매시 : 업체별로 상이한 배송비 적용    * 세트상품의 경우 부분취소 시 추가 배송비가 부과될 수 있습니다.    * 북카트에서 배송비없애기 버튼을 클릭하셔서, 동일업체상품을 조금 더 구매하시면, 배송비를 절약하실 수 있습니다. 해외배송 안내 인터파크도서에서는 국내에서 주문하시거나 해외에서 주문하여 해외로 배송을 원하실 경우 DHL과 특약으로 책정된 요금표에    의해 개인이 이용하는 경우보다 배송요금을 크게 낮추며 DHL(www.dhl.co.kr)로 해외배송 서비스를 제공합니다. 해외배송은 도서/CD/DVD 상품에 한해 서비스하고 있으며, 다른 상품을 북카트에 함께 담으실 경우 해외배송이 불가합니다. 해외주문배송 서비스는 인터파크 도서 회원 가입을 하셔야만 신청 가능합니다. 알아두세요!!! 도매상 및 제작사 사정에 따라 품절/절판 등의 사유로 취소될 수 있습니다. 오픈마켓업체의 배송지연시 주문이 자동으로 취소될 수 있습니다. 출고가능 시간이 서로 다른 상품을 함께 주문할 경우 출고가능 시간이 가장 긴 기준으로 배송됩니다. 유통의 특성상 출고기간은 예정보다 앞당겨지거나 늦춰질 수 있습니다. 택배사 배송일인 서울 및 수도권은 1~2일, 지방은 2~3일, 도서, 산간, 군부대는 3일 이상의 시간이 소요됩니다.